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Trace elements in soils of the Antarctic ice-free areas: Insights on natural geochemical values, anthropogenic impact and possible remobilisation upon permafrost thaw

dc.contributor.authorZilhão, Henrique
dc.contributor.authorCesário, Rute
dc.contributor.authorVieira, Gonçalo
dc.contributor.authorCanário, João
dc.date.accessioned2025-06-30T09:28:56Z
dc.date.available2025-06-30T09:28:56Z
dc.date.issued2025
dc.description.abstractClimate change is transforming the ice-free areas of Antarctica, leading to rapid changes in terrestrial ecosystems. These areas represent <0.5% of the continent and coincide with the most anthropogenically pressured sites, where the human footprint is a source of contamination. Simultaneously, these are the locations where permafrost can be found, not being clear what might be the consequences following its degradation regarding trace element remobilisation. This raises the need for a better understanding of the natural geochemical values of Antarctic soils as well as the extent of human impact in the surroundings of scientific research stations. Permafrost thaw in the Western Antarctic Peninsula region and in the McMurdo Dry Valleys is the most likely to contribute to the remobilisation of toxic trace elements, whether as the result of anthropogenic contamination or due to the degradation of massive buried ice and ice-cemented permafrost. Site-specific locations across Antarctica, with abandoned infrastructure, also deserve attention by continuing to be a source of trace elements that later can be released, posing a threat to the environment. This comprehensive summary of trace element concentrations across the continent's soils enables the geographical systematisation of published results for a better comparison of the literature data. This review also includes the used analytical techniques and methods for trace element dissolution, important factors when reporting low concentrations. A new perspective in environmental monitoring is needed to investigate if trace element remobilisation upon permafrost thaw might be a tangible consequence of climate change.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationZilhão, H., Cesário, R., Vieira, G. & Canário, J. (2025). Trace elements in soils of the Antarctic ice-free areas: Insights on natural geochemical values, anthropogenic impact and possible remobilisation upon permafrost thaw. Earth-Science Reviews, 268, 105171. https://doi.org/10.1016/j.earscirev.2025.105171pt_PT
dc.identifier.doi10.1016/j.earscirev.2025.105171pt_PT
dc.identifier.issn0012-8252
dc.identifier.urihttp://hdl.handle.net/10400.5/101859
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationTHAWIMPACT (2022.06628.PTDC)pt_PT
dc.relationCentro de Química Estrutural
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0012825225001321?via%3Dihubpt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectTrace elementspt_PT
dc.subjectContaminantspt_PT
dc.subjectAntarctica ice-free areaspt_PT
dc.subjectPermafrostpt_PT
dc.subjectClimate changept_PT
dc.titleTrace elements in soils of the Antarctic ice-free areas: Insights on natural geochemical values, anthropogenic impact and possible remobilisation upon permafrost thawpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleCentro de Química Estrutural
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/OE/2021.06290.BD/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00100%2F2020/PT
oaire.citation.startPage105171pt_PT
oaire.citation.titleEarth-Science Reviewspt_PT
oaire.citation.volume268pt_PT
oaire.fundingStreamOE
oaire.fundingStream6817 - DCRRNI ID
person.familyNameBrito Guapo Teles Vieira
person.givenNameGonçalo
person.identifierG-5958-2010
person.identifier.ciencia-id2519-6583-CAEA
person.identifier.orcid0000-0001-7611-3464
person.identifier.scopus-author-id7005863976
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication7039fbb2-e1f8-4c3e-80f1-603b12d33c1c
relation.isAuthorOfPublication.latestForDiscovery7039fbb2-e1f8-4c3e-80f1-603b12d33c1c
relation.isProjectOfPublication5b2a97b1-4d0d-422b-8555-00c8226bbc8d
relation.isProjectOfPublication6f563b11-7a3d-4ed6-9d77-235805ada8d4
relation.isProjectOfPublication.latestForDiscovery6f563b11-7a3d-4ed6-9d77-235805ada8d4

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