Browsing by Author "Cabral, F."
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- Assessment of CO2 emissions during acidification, storage and after incorporation to soil of pig slurryPublication . Fangueiro, D.; Gusmão, M.; Surgy, S.; Cabral, F.Large amounts of pig slurry are produced each year in Portugal leading to environmental problems such as water and air pollution. Previous studies have reported that livestock production is the main source of anthropogenic ammonia (NH3) emissions in Europe (Kai et al., 2008) and an important source of greenhouse gases (Weiske and Petersen, 2006). Effluent treatment has been promoted to improve slurry management and to reduce its environmental impact (Sommer and Hutchings, 2001, Fangueiro et al., 2008a). Solid-liquid separation of slurry is a useful tool at the farm level producing valuable fractions, a liquid that can be used for direct fertilisation and a solid fraction that can be composted (Fangueiro et al., 2008b). Alternatively, acidification of slurry has been proposed to reduce ammonia (NH3) emissions during storage and field application (Kai et al., 2008). Previous works (Misselbrook et al., 2005; Fangueiro et al., 2008a) reported that higher NH3 emissions occurred during storage of liquid fraction of slurry or manure with low dry matter content, probably due to a reduced crust formation that decreases NH3 emissions. Hence, acidification of the liquid fraction of slurry is strongly recommended. Slurry acidification is common practice in The Netherlands and Denmark (Schils et al., 1999; Eriksen et al., 2008) but this technology still needs to be improved to avoid hazards. It is expected that this technology will be used in more countries since the European Directive (2001/81/CE) demands a decrease of atmospheric pollutants such as NH3: targets for lower NH3 emissions have been already set in Spain (Castrillon et al., 2009). Nevertheless, the acidification process leads to significant carbon dioxide (CO2) emissions (Vandré and Clemens, 1997). Such CO2 release is problematic when a closed system of slurry acidification is used (when acidified slurry is flushed back to pig houses) since it may lead to foam formation (Vandré and Clemens, 1997; Borst, 2001). Nevertheless, Fangueiro et al. (2010) reported that acidification of slurry or derived fractions led to a decrease in CO2 emissions following soil addition relative to non acidified materials. The aim of the present work was to measure the CO2 emissions during the acidification process of the liquid fraction of pig slurry and its subsequent impact during storage and after soil incorporation.
- Assessment of N mineralization and leaching in soil using a new in-situ incubation methodPublication . Cabral, F.; Sousa, J.R.; Coutinho, J.Towards sustainable soil management, the application of organic residues to the soil has to be based on criteria sustained by experimental studies. Several methods for estimating the amount of N that mineralizes from landapplied organic residues can be used but laboratory incubations has been the main methodology used due to several advantages related to practical and economical aspects (Qafoku et al., 2001). However, this type of methodology is performed under controlled temperature and moisture content, at optimal conditions for the mineralization process, limiting the extrapolation of laboratory derived values to the field conditions (Hanselman et al., 2004). Since N mineralization process can be affected by the dynamic of these factors, several authors consider field incubations as a more realistic method to assess N mineralization (Subler et al., 1995; Halselman et al., 2004). Nevertheless, the quality of the results obtained depends on the type of reactor devices used for measuring N mineralization under these conditions. In fact, various reactors devices described in the specific literature, like buried bags (Eno, 1960) or covered cylinders (Raison et al., 1987), reveal some disadvantages or limitations in monitoring N mineralization in field conditions. More recently, refining reactor devices, by introducing exchange resins, promoted a more sensible indicator comparatively to other methods since temperature, moisture content and aeration inside the containerized soil are close to undisturbed soil (Halselman et al., 2004). Considering that resin-trap incubation is the most promising in-situ technology in measuring nitrogen net mineralization rates from organic soil amendments, the aim of the present study is to evaluate the quality of the results obtained by using a new in-situ incubation device for the determination of N mineralization kinetics in the soil as well as the potential of nitrogen leaching as a potential alternative use in field studies of N mineralization kinetics from organic residues applied to soils.
- Carbon and nitrogen mineralization of organic wastes from sugarcane distilleries: vinasse and yeast wastePublication . Vasconcelos, E.; Cabral, F.; Pita, V.; Fangueiro, D.; Ribeiro, H.M.In Madeira Island (Portugal) significant amounts of wastes are generated in sugarcane distilleries, namely vinasse (the remaining fermented must after distillation) and yeast waste (the yeast surplus produced during the alcoholic fermentation). These wastes have high organic loads and low pH, leading to serious environmental problems when released directly into natural watercourses or when poorly managed (Hati et al., 2007). As a solution to avoid expensive treatments, both wastes have been used as soil amendment, since they contain important amounts of plant nutrients and organic matter (Resende et al., 2006; Parnaudeau et al., 2008). Indeed, application to soils of vinasse is a common practice in sugarcane cultivated areas and can fully substitute K and partially P on crops fertilization. Nevertheless, additional mineral nitrogen fertilization is needed when vinasse is spread in the soils (Junior et al., 2007; Oliveira et al., 2009). On the other hand, yeast waste has been considered as an excellent potential source of nitrogen for plant nutrition when applied to soils (Rezende et al., 2004). Thus, combined application of both wastes should ensure a more balanced supply of nutrients to plants. However, scarce information is available on the combine use of both wastes as fertilizer. The main objective of this study is to assess the effect of the combined application to soil of both organic materials (vinasse and yeast waste), and to evaluate its subsequent effects on nitrogen mineralization/immobilization process to supply nitrogen to crops and to preserve/restore soil carbon.
- Influence of the particle size and animal slurry type on the potential of nitrogen mineralization after soil incorporationPublication . Fangueiro, D.; Gusmão, M.; Grilo, J.; Vasconcelos, E.; Cabral, F.Animal manures are rich in organic matter and nutrients, namely nitrogen (N) and, consequently, widely applied to soil as organic fertilizers. However, a large part of the nitrogen contained in animal manures is in the organic form and so not directly available for plants. Indeed, organic N has to be mineralized prior to plant uptake (Rees and Castle, 2002). Several manure characteristics as the C:N ratio (Chadwick et al., 2000), the lignin content (Kristensen, 1996) and the NH4 +/organic N ratio (Beauchamp and Paul, 1989) have been suggested as indicators of the plant-available N. More recently, Fangueiro et al. (2008) showed that the potential of N mineralization (PNM) of cattle slurry is inversely correlated with slurry particle size: finest fractions are the particle-size fractions from which N mineralization occurs in slurries whereas coarser fractions are associated with immobilization. Furthermore, Moller et al. (2002) reported that animal diet and anaerobic decomposition during storage in slurry channels and stores affect the slurry particle size distribution. Such information is of great interest since the finest slurry particle size should infiltrate the soil more easily and quickly relative to the coarser slurry particle size that should remain close to soil surface. Furthermore, mechanical slurry separation is now performed in many pig and dairy farms in order to improve slurry management in terms of nutrients utilization and reducing costs related to slurry storage. Slurry separation by screw press leads to a nutrient rich organic solid fraction (0.7– 3.2 mm particles) that may be composted and a liquid fraction that can be used for fertigation. In the present study, three types of slurry (pig, duck and cattle) were separated into 4 slurry particle size fractions (>2000 um, 2000-500 um, 500-100 um, <100 um) in order to assess the influence of the type of slurry and slurry particle size on the PNM after soil incorporation.
- Proportion, composition and potencial N mineralisation of particle size fractions obtained by mechanical separation of animal slurryPublication . Fangueiro, D.; Gusmão, M.; Grilo, J.; Porfirio, G.; Vasconcelos, E.; Cabral, F.Mechanical slurry separation is a useful technology for slurry management on farms. The characteristics of the fractions obtained depend on the separation efficiency and on the characteristics of the original slurry. In the present work, three types of slurry e pig, cow and duck e were separated into 4 particle size fractions. The proportion, composition in terms of carbon and nutrients as nitrogen (N) phosphorus (P) and potassium (K) was evaluated. The potential of N mineralisation of whole slurries, and each fraction after soil application, was assessed. Results of the study showed that the characteristics of the slurry fractions obtained depend strongly on the slurry type considered, namely on its dry matter (DM) content. A positive value of PNM was observed with the 3 slurry types and 4 fractions considered, indicating that no N immobilisation occurred. Nevertheless, results showed that the value of PNM vary significantly (P < 0.05) with slurry types and slurry particle size fractions.
- Short-term effects on soil properties and wheat production from secondary paper sludge application on two Mediterranean agricultural soilsPublication . Nunes, J. Rato; Cabral, F.; López-Piñeiro, A.This study was conducted under greenhouse conditions to evaluate the potential use of SPS as a fertilizer, amendment and/or liming agent for wheat (Triticum aestivum L.). Two representative Mediterranean agricultural soils, a Cambic Arenosol (cmAR) and a Cromic Cambisol (crCM) were used. Treatments included four sludge rates ranging from 0 to 40 g kg 1 (equivalent of 0, 38, 88 and 120 Mg ha 1). A significant increment in soil pH, organic carbon, N total, available P and exchangeable K were observed in both soils. Sludge application significantly increased N and decreased Zn, Mn and Cu concentrations in wheat. Wheat grain yields were reduced by 33% and 37% when 120 Mg SPS ha 1 was applied to cmAR and crCM soils, respectively, due apparently to unavailability of Mg. However, straw yields, with much lower Mg requirements, increased significantly with SPS rates. Secondary pulp mill sludge seems to be a potential source of organic matter, N, P, K and a potential soil amendment liming agent for acid soils, when appropriate supplemental fertilizer was provided. For grain crops grown in these soils, addition of Mg is required for proper nutrient balance.
- Use of pulp mill inorganic wastes as alternative liming materialsPublication . Cabral, F.; Ribeiro, H.M.; Hilário, L.; Machado, L.; Vasconcelos, E.A laboratory aerobic incubation study was performed during 18 weeks under controlled conditions to assess the effects of applying different doses of pulp mill inorganic wastes on the physical–chemical properties of an acid Dystric Cambissol. Three different inorganic wastes were tested – wood ash, dregs and grits, and an agriculture limestone was used as reference. Results showed that increasing the dose applied of the different inorganic wastes tested always led to significant raises of soil pH at different incubation times demonstrating that its use as alternative-liming materials could be a valid and less expensive option to the use of commercial agricultural limestone. Moreover, no immediate concerns seem to be expected related to soil exchangeable sodium (Na) content, at least for the doses needed to increase soil pH until the targeted value 6.5. Particularly for wood ash a pronounced increase on soil extractable potassium and phosphorous was observed, indicating that besides the liming effect this waste can contribute to improve soil fertility by supplying significant available amounts of these nutrients. Finally, metals do not seem to be a limiting factor for the application to land of these byproducts