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Carbon Footprint Assessment of Microalgal Biomass to Bio-jet Fuel in Mainland Portugal

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Resumo(s)

The aviation industry, a significant contributor of greenhouse gases emissions in the transportation sector, faces challenges meeting the decarbonization targets until 2050 through the paradigm of electric mobility. The limitations of electrifying aviation emphasize the importance of exploring alternative solutions, particularly biofuels. Hence, this study took part in the Move2LowC project, exploring microalgae cultivation in industrial wastewater using industrial CO2 effluents, microalgae harvesting, and its conversion through hydrothermal liquefaction (HTL), bio-oil refining/upgrading to bio-jet fuel, and combustion in a jet engine, in mainland Portugal. The primary goal was to determine the carbon footprint of microalgae to bio-jet fuel and other useful refinery products, addressing two research questions (RQ): RQ1 – What is the carbon footprint of converting 1 kg (dry cell weight) (FU) of microalgae into multi-product, in gCO2eq/FU?; and RQ2 – What is the carbon footprint of obtaining and burning 1 MJ of bio-jet fuel (FU) from microalgae, in gCO2eq/FU, and how can it achieve SAF (Sustainable Aviation Fuel) compliance? A life cycle analysis (LCA) was undertaken, following ISO 14040/44 standards and global warming potential at 100years (GWP100), incorporating experimental Move2LowC data, and from literature and modeling through PRELIM. The system boundary considered cultivation, harvesting, HTL, transport to refinery, refining/upgrading, transport to airport, and combustion, excluding construction materials. RQ2 incorporated energy allocation to bio-jet fuel, to compare with CORSIA guidelines. Alternative scenarios were analyzed, exploring the influence on GWP100 results of the process units locations; bottled CO2 supplementation; heat recovery from HTL syngas; 100 % renewable electricity; and different thermochemical processes’ yields. Results indicated that the Move2LowC base-case scenario does not currently enable SAF production, with a carbon footprint (161.45 gCO2eq/MJ bio-jet fuel) significantly exceeding that of conventional jet-fuel. Electricity for cultivation and heat for HTL were major contributors. The scenario analysis revealed opportunities for emission reduction through employing heat recovery and locating all system at the same facilities. Combining these two measures, the best-case scenario could produce SAF if electricity was zero emissions, even with lower bio-oil and bio-jet fuel yields. This study highlights the importance of optimizing the Move2LowC process and, despite current limitations, presents potential pathways for SAF compliance, including the decarbonization of the Portuguese electricity mix by 2050.

Descrição

Tese de mestrado, Engenharia da Energia e Ambiente, 2024, Universidade de Lisboa, Faculdade de Ciências

Palavras-chave

Águas residuais Liquefação Hidrotérmica (HTL) Gás de síntese Simulação de refinaria (PRELIM) jet fuel sustentável (SAF) Teses de mestrado - 2024

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Licença CC