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Environmental Risk Assessment of Glyphosate and Aminomethylphosphonic Acid (AMPA) in Portuguese Groundwater Ecosystems

dc.contributor.authorSantos, Inês
dc.contributor.authorLopes, Ana
dc.contributor.authorSilva, Emília
dc.date.accessioned2025-08-14T08:49:42Z
dc.date.available2025-08-14T08:49:42Z
dc.date.issued2024-11
dc.description.abstractThe aim of the present study was to assess the risk related to the exposure of groundwater ecosystems to herbicide glyphosate and its non-relevant metabolite aminomethylphosphonic acid (AMPA) based on the quotient between measured concentrations gathered from the Water Resources Information System of Portugal, and groundwater quality standards set in legislation and estimated from environmental quality standards in surface waters. Glyphosate was analyzed in 103 ground- water samples collected from 80 wells located in 21 aquifer systems from the four hydrogeological units of mainland Portugal, between 2019 and 2021. It was detected in 14% of the total samples; however, only 10% presented concentration levels above 0.1 μg/L, the groundwater quality stan- dard, and none of these values exceeded the value of 8.67 μg/L estimated from the annual average environmental quality standard proposed for glyphosate in surface waters. In comparison, AMPA was detected in only 5% of 63 groundwater samples, in four dug wells. In both compounds, the maximum concentration level was quantified in a dug well located in the O25-Torres Vedras aquifer system, from the Western unit, with 4.69 and 4.24 μg/L for glyphosate and AMPA, respectively. The results of this study demonstrate that it is extremely important to raise awareness and offer training to farmers on the sustainable use of plant protection products and good agricultural practices, in order to prevent groundwater contamination and improve its quality. There is also an urgent need to carry out ecotoxicological tests with further groundwater species from different functional groups in order to obtain a quality standard that accurately represents the groundwater communities.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationInês, S.; Ana, L.; Silva, E. Environmental Risk Assessment of Glyphosate and Aminomethylphosphonic Acid (AMPA) in Portuguese Groundwater Ecosystems. Environments 2024, 11, 258. https://doi.org/10.3390/environments11110258pt_PT
dc.identifier.doi10.3390/environments11110258pt_PT
dc.identifier.urihttp://hdl.handle.net/10400.5/102860
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherMDPIpt_PT
dc.relation.publisherversionhttps://www.mdpi.com/journal/environmentspt_PT
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt_PT
dc.subjectAMPApt_PT
dc.subjectglyphosatept_PT
dc.subjectgroundwaterpt_PT
dc.subjectgroundwater quality standardspt_PT
dc.subjectPortugalpt_PT
dc.titleEnvironmental Risk Assessment of Glyphosate and Aminomethylphosphonic Acid (AMPA) in Portuguese Groundwater Ecosystemspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.issue11pt_PT
oaire.citation.startPage258pt_PT
oaire.citation.titleEnvironmentspt_PT
oaire.citation.volume11pt_PT
person.familyNameSilva
person.givenNameEmília
person.identifier.ciencia-idBF17-D68D-B0D4
person.identifier.orcid0000-0002-7498-8926
person.identifier.ridL-6523-2015
person.identifier.scopus-author-id7201854698
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationc7032abe-890a-4e98-b672-40123b57c8bd
relation.isAuthorOfPublication.latestForDiscoveryc7032abe-890a-4e98-b672-40123b57c8bd

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